Help! Lightroom

I'm going mad .... with Lightroom and Adobe CS6!
I'll open a file (Raw, Jpeg or Tiff) and adjust the colours in 'Develop' to get perfect beautiful reds but when I switch to 'Library' the reds change to orange! So, no matter what I do to the reds, when I export them the red has changed to orange. This has only started happening recently.
In all other programs (Faststone etc.) the reds are perfect....except adobe cs6' where they are also orange.

I calibrate my monitor using 'Huey' and have done for years without any problem

This problem is only with red, as all other colours are fine.

Even if I open (edited) images from years ago I get the same problem

Please save my sanity!!!!

When you export from the develop module do the reds turn orange?

It depends which program i open them with after exporting, if i open them in lightroom or photoshop they're orange, if i open them in anything else they are red.
Inidentally, i uploaded one to facebook and that was orange!

Are you using the same rgb in both programmes???

That colour difference (reds to orange) I have found can sometimes be caused by a colour mode mismatch - eg if you are carrying out saturation or vibrance type operations in a LAB colour mode. Check your LR develop module settings to make sure you are carrying out the process in a standard sRGB mode, assuming this is your intended output colourspace.

My preferred editor, Sagelight, has a number of buttons to switch between these different modes, making it easy to control (and make a mistake!) - I don't know the LR interface, but its worth checking there's nothing buried deep somewhere.

Cabstar.....yes, I'm using Srgb in all programs

Have a look at this thread....link